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排序方式: 共有145条查询结果,搜索用时 31 毫秒
61.
Laleh Safari Denys Iablonskyi Filippo Fratini 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2014,68(2):1-8
We present secondary phase identification studies on Cr doped ZnO nanoparticles prepared by the sol-gel method. X-ray diffraction analysis confirms the formation of chromium oxides and there is found to be an increase of lattice parameter with thermal annealing. Scanning electron microscopic studies show the increase in the crystalline nature and particle size. Optical absorption measurements of the as prepared sample exhibit a strong band at 356 nm due to the free exciton absorption of the ZnO nanoparticles. An absorption band at 277 nm is due to the 3T1 → 3T2 transition in Cr4+ ions which appears only for the annealed samples. Photoluminescence studies show that deep level emission is completely suppressed after Cr2O3 formation/thermal annealing. Raman and FTIR spectra reveal formation of the Cr2O3 phase. Thermal annealing leads to the increase of crystalline nature which gives an enhancement to the Raman modes. 相似文献
62.
Amir Safari 《Computational Statistics》2014,29(6):1447-1468
According to the Statistical Learning Theory, the support vectors represent the most informative data points and compress the information contained in training set. However, a basic problem in the standard support vector machine is that when the data is noisy, there exists no guaranteed scheme in support vector machines’ formulation to dissuade the machine from learning noise. Therefore, the noise which is typically presents in financial time series data may be taken into account as support vectors. In turn, noisy support vectors are modeled into the estimated function. As such, the inclusion of noise in support vectors may lead to an over-fitting and in turn to a poor generalization. The standard support vector regression (SVR) is reformulated in this article in such a way that the large errors which correspond to noise are restricted by a new parameter \(E\) . The simulation and real world experiments indicate that the novel SVR machine meaningfully performs better than the standard SVR in terms of accuracy and precision especially where the data is noisy, but in expense of a longer computation time. 相似文献
63.
Copper complexes, [Cu(dm4bt)Cl(Hipht)] (1) and [{Cu(dm4bt)(H2O)(ipht)}4·2H2O] (2) (where dm4bt is 2,2′-dimethyl-4,4′-bithiazole, Hipht is hydrogen isophthalate and ipht is isophthalate) have been synthesized. These two complexes were characterized by IR, UV–Vis and EPR spectroscopy. Moreover; their single-crystal structures were studied by the X-ray diffraction method. Complex 1 has a monomer structure and copper has accepted a distorted square pyramidal structure. Isophthalic acid in 1 lost one of its protons and produced one bidentate carboxylate and one free carboxylic acid. Controlled deprotonation in the presence of ethylene diamine results in self-assemblies of 1 to form a tetramer complex of 2. Complex 2 has two kinds of spatial isomers which are resolved by EPR and X-ray. 相似文献
64.
The self-assembly of a new flexible tritopic pyrazine-pyridine ligand (pz-3-py) with HgX(2) (X = Cl, Br) was investigated. The results show that coordinated chloride and bromide anions play different roles, and two architecturally different coordination polymers were obtained with the anions used. Where X = Cl, in [Hg(μ(3)-pz-3-py)Cl(2)](n) (1), the 2D network is isolated, while for X = Br, in [Hg(μ-pz-3-py)Br(2)](n) (2), a 1D zigzag chain is constructed. Our results show that noncovalent interactions such as hydrogen bond, halogen···halogen, and halogen···π interactions, when acting cooperatively, are driving forces for the selection of different structures. 相似文献
65.
Safari Mukeru 《Applied Mathematics Letters》2012,25(12):2168-2173
66.
A green and convenient approach to the synthesis of 2-amino-4,6-diphenylnicotinonitriles via four-component reaction of malononitrile, aromatic aldehydes, acetophenone derivatives and ammonium acetate in water under ultrasound irradiation is described. The combinatorial synthesis was achieved for this methodology with applying ultrasound irradiation while making use of water as green solvent. In comparison to conventional methods, experimental simplicity, good functional group tolerance, excellent yields, short routine, and selectivity without the need for a transition metal or base catalyst are prominent features of this sonocatalyzed procedure. 相似文献
67.
Amani V Safari N Khavasi HR 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2012,85(1):17-24
[Fe(3)(μ(3)-O)(μ-OAc)(6)(py)(3)][FeBr(4)](2)[py·H], complex (1), (OAc is acetate) was prepared from the reaction of FeBr(3) with pyridine in 1.2 molar aqueous HBr and 2.4 molar aqueous CH(3)COOH. Recrystallization of 1 in acetonitrile produced the [Fe(3)(μ(3)-O)(μ-OAc)(6)(py)(3)][FeBr(4)] complex (2). Both complexes were characterized by IR and (1)H NMR spectroscopies and their structures were studied using the single-crystal diffraction method. There is a lack of thorough characterization of the titled compounds in solution. Paramagnetic (1)H NMR is introduced as a good probe for the characterization of a family of titled compounds in solution when the L ligand coordinated to iron varies as: CH(3)OH, CH(3)CN, DMSO, H(2)O, py and acetone. 相似文献
68.
69.
A kinetic method for measuring the relative rates of hydroxylation of naphthalene derivatives/cyclohexene has been developed. With this technique a linear relationship between the logarithm of the rates of oxidation products and the oxidation potentials of the naphthalene derivatives has been observed. Plots of σ Hammett and σ+ Hammett–Brown with logarithm of relative rates have been linear and shown ρ = −0.98 and ρ+ = −0.58, respectively. This contrast aromatic oxidation in protic solvents in which the oxidation products are naphthoquinones and provides further evidence for the intermediacy of carbocation in the hemin catalyzed hydroxylation of aromatic rings. 相似文献
70.
Nader Noroozi Pesyan Hamid Rashidnejad Mohammad Ali Esmaeili Elnaz Safari Tuncay Tunç Mostafa Alilou Reihaneh Safavi-Sohi Ertan Şahin 《中国化学会会志》2020,67(9):1679-1695
The reaction of symmetrical (thio)barbituric acids with aldehydes in the presence of 4-methyl morpholine yielded a new form of 4-methyl morpholinium bis-(thio)barbiturate containing charge-separated intermolecular and eight-membered intramolecular H-bonds. X-ray Crystallography, FT-IR, and 1H and 13C-NMR spectroscopy techniques were used for structure characterizations. Some of these compounds showed potent anticancer activities. Cytotoxicity of the synthetic compounds against HeLa and MCF-7 cell lines were performed by MTT assay. In addition, a comparative molecular field analysis was carried out, and the effects of substituents on the biological activities of these compounds were explained. 相似文献